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纳米晶TiO₂/ZnO薄膜:制备及其在染料敏化太阳能电池中的应用

Nanocrystalline TiO2/ZnO thin films: fabrication and application to dye-sensitized solar cells.

作者信息

Mane Rajaram S, Lee Won Joo, Pathan Habib M, Han Sung-Hwan

机构信息

Inorganic Nano-Materials Laboratory, Department of Chemistry, Hanyang University, Sungdong-Ku, Haengdang 17, Seoul 133-791, Republic of Korea.

出版信息

J Phys Chem B. 2005 Dec 29;109(51):24254-9. doi: 10.1021/jp0531560.

DOI:10.1021/jp0531560
PMID:16375421
Abstract

Nanocrystalline TiO2 thin films composed of densely packed grains were deposited onto indium-doped tin oxide (ITO)-coated glass substrates at room temperature using a chemical bath deposition technique. A layer-by-layer (LbL) process was utilized to obtain a 1.418-microm-thick TiO2/ZnO structure. The TiO2 surface was super-hydrophilic, but its hydrophilicity decreased considerably after ZnO deposition. Other TiO2/ZnO films were studied to assess their suitability as photoelectrodes in dye-sensitized solar cells (DSSCs).

摘要

采用化学浴沉积技术,在室温下将由紧密堆积晶粒组成的纳米晶二氧化钛薄膜沉积到涂有铟掺杂氧化锡(ITO)的玻璃基板上。利用逐层(LbL)工艺获得了厚度为1.418微米的二氧化钛/氧化锌结构。二氧化钛表面具有超亲水性,但在沉积氧化锌后其亲水性显著降低。还对其他二氧化钛/氧化锌薄膜进行了研究,以评估它们作为染料敏化太阳能电池(DSSC)光电极的适用性。

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