Authelin Jean-René
Chemical Development Department, Centre de Recherches de Vitry sur Seine, 13 Quai Jules Guesdes, 94400 Vitry sur Seine, France.
Int J Pharm. 2005 Oct 13;303(1-2):37-53. doi: 10.1016/j.ijpharm.2005.07.007.
Different physical and mathematical models of non-stoichiometric hydrates derived form previous work in inorganic hydrates are reviewed. A theoretical link between the order of water molecules in the hydrate and the shape of the isotherm is outlined. The comparison of the models with sorption isotherms and structural data of well-known cases from the literature and one in-house case shows that the model can fit many experimental situations and is in good agreement with qualitative assessments of the order in the hydrates.
回顾了从先前无机水合物研究中推导出来的非化学计量水合物的不同物理和数学模型。概述了水合物中水分子排列顺序与等温线形状之间的理论联系。将这些模型与文献中知名案例以及一个内部案例的吸附等温线和结构数据进行比较，结果表明该模型能够拟合许多实验情况，并且与水合物中排列顺序的定性评估结果高度一致。
