Unusual gold(I)-catalyzed isomerization of 3-hydroxylated 1,5-enynes: highly substrate-dependent reaction manifolds.
作者信息
Gagosz Fabien
机构信息
Laboratoire de Synthèse Organique, Ecole Polytechnique, 91128 Palaiseau, France.
出版信息
Org Lett. 2005 Sep 15;7(19):4129-32. doi: 10.1021/ol051397k.
PMID:16146369
Abstract
[reaction: see text] The gold(I) isomerization of diversely substituted 3-hydroxylated enynes has led to the discovery of three new unreported skeletal rearrangements furnishing structures such as alkylidene-cyclopentenes, cyclohexadienes or alpha,beta-unsaturated aldehydes under very mild conditions.
摘要
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