通过轮烷的机械键进行荧光共振能量转移。
Fluorescence resonance energy transfer across a mechanical bond of a rotaxane.
作者信息
Onagi Hideki, Rebek Julius
机构信息
The Skaggs Institute for Chemical Biology and The Department of Chemistry, The Scripps Research Institute, MB-26, 10550 North Torrey Pines Road, La Jolla, CA 92037, USA.
出版信息
Chem Commun (Camb). 2005 Sep 28(36):4604-6. doi: 10.1039/b506177f. Epub 2005 Aug 18.
DOI:10.1039/b506177f
PMID:16158129
Abstract
Fluorescence transfer across a donor-acceptor tagged rotaxane was studied and a small conformational change of the rotaxane observed using fluorescent spectroscopy and ROESY NMR.
摘要
研究了荧光在供体-受体标记的轮烷上的转移，并使用荧光光谱和ROESY NMR观察到轮烷的微小构象变化。
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