Maji Tapas Kumar, Kaneko Wakako, Ohba Masaaki, Kitagawa Susumu
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishigyo-ku, Kyoto 615-8510, Japan.
Chem Commun (Camb). 2005 Sep 28(36):4613-5. doi: 10.1039/b507953e. Epub 2005 Aug 19.
Two novel 3D isomorphous organic-inorganic hybrid frameworks, [M(1,4-napdc)]n ( M = Co(II), and Mn(II), ; 1,4-napdcH2 = napthalene-1,4-dicarboxylic acid) have been hydrothermally synthesized and structurally characterized, and the magnetic results exhibit metamagnetic behaviour (TC = 5.5 K), and a weak antiferromagnetic interaction, which are structurally correlated.
通过水热法合成并对其结构进行了表征，得到了两种新型的三维同构有机-无机杂化骨架化合物[M(1,4-napdc)]n（M = Co(II)和Mn(II)；1,4-napdcH2 = 萘-1,4-二甲酸），其磁性结果显示出变磁行为（TC = 5.5 K）以及弱反铁磁相互作用，这些在结构上是相关联的。
