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弹性磷酸锌晶格中的离散水六聚体与模板辅助分子识别

Discrete water hexamers and template-assisted molecular recognition in an elastic zincophosphate lattice.

作者信息

Liao Yueh-Chun, Jiang Yao-Chen, Wang Sue-Lein

机构信息

Department of Chemistry, National Tsing Hua University Hsinchu 30043, Taiwan.

出版信息

J Am Chem Soc. 2005 Sep 21;127(37):12794-5. doi: 10.1021/ja054357k.

DOI:10.1021/ja054357k
PMID:16159261
Abstract

Water molecules and terephthalic acid, respectively, exist as a self-assembled monolayer of cyclic (H2O)6 clusters and (TA)infinity chiral chains between the zincophosphate sheets (in blue wires); the irremovable template H3tren3+ ions (in purple wires) are dynamic and could translate back and forth on the sheets during the conversion of the supramolecule contained in one another.

摘要

水分子和对苯二甲酸分别以环状(H₂O)₆簇的自组装单分子层和磷酸锌片层(蓝色线条)之间的(TA)∞手性链形式存在;不可去除的模板H₃tren³⁺离子(紫色线条)是动态的,在相互包含的超分子转化过程中可在片层上来回移动。

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