Notte Gregory T, Sammakia Tarek, Steel Peter J
Department of Chemistry and Biochemistry, University of Colorado, Boulder, Colorado 80309-0215, USA.
J Am Chem Soc. 2005 Oct 5;127(39):13502-3. doi: 10.1021/ja053743z.
The kinetic resolution of alpha-acetoxy N-acyl oxazolidinethiones using the chiral, nonracemic O-nucleophilic acyl transfer catalyst 8 is described. The reaction proceeds on a variety of substrates in excellent yields, with s-factors ranging from 17 to 31.
描述了使用手性、非外消旋的O-亲核酰基转移催化剂8对α-乙酰氧基N-酰基恶唑烷硫酮进行动力学拆分。该反应在多种底物上以优异的产率进行，s-因子范围为17至31。
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