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基于稀土铽配合物的电致发光器件

[Electroluminescent device based on rare earth terbium complex].

作者信息

Zhang Meng-xin, Deng Zhen-bo, Bai Feng, Zhang Zhi-feng, Xu Deng-hui, Liang Chun-jun, Wang Rui-fen

机构信息

Institute of Optoelectronics, Key Laboratory of Information Storage and Display, Beijing Jiaotong University, Beijing 100044, China.

出版信息

Guang Pu Xue Yu Guang Pu Fen Xi. 2005 Jun;25(6):836-9.

Abstract

Rare earth complex TbY(m-MBA)6 (phen)2.2H20 have been synthesized, which were used as emitting materials in electroluminescence. Single-layer devices and bilayer devices with Alq as electron transmission layer have been fabricated. The electroluminescent properties of the devices were studied. The electroluminescent mechanism of the devices was proposed by measuring and analyzing the emission and the excitation spectra of the emissive layer. Y3+ may play the role to promote the energy transfer from ligand to Tb3+ and the possible energy transfer process of the device was preliminarily discussed.

摘要

已合成稀土配合物TbY(m-MBA)6(phen)2·2H2O,并将其用作电致发光中的发光材料。制备了以Alq作为电子传输层的单层器件和双层器件。研究了器件的电致发光性能。通过测量和分析发光层的发射光谱和激发光谱,提出了器件的电致发光机理。Y3+可能起到促进能量从配体转移到Tb3+的作用,并初步讨论了器件可能的能量转移过程。

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