Saito Shinichi
Department of Chemistry, Faculty of Science, Tokyo University of Science, Japan.
Yakugaku Zasshi. 2005 Oct;125(10):771-84. doi: 10.1248/yakushi.125.771.
In this review we report our development and applications of the highly selective cycloaddition reactions of unsaturated hydrocarbons such as conjugated enynes, electron-deficient allenes, and electron-deficient methylenecyclopropanes in the presence of nickel and palladium catalysts. Homocoupling reactions as well as co-cyclization reactions proceed with high atom economy, which is an attractive feature of these reactions. The efficient synthesis of 4-7 membered carbocycles was achieved.
在本综述中，我们报告了在镍和钯催化剂存在下，共轭烯炔、缺电子丙二烯和缺电子亚甲基环丙烷等不饱和烃的高选择性环加成反应的开发及应用。均偶联反应以及共环化反应均以高原子经济性进行，这是这些反应的一个吸引人的特点。实现了4至7元碳环的高效合成。
