Ishiyama Tatsuo, Sato Kazuaki, Nishio Yukihiro, Saiki Takeaki, Miyaura Norio
Division of Chemical Process Engineering, Graduate School of Engineering, Hokkaido University, Sapporo, 060-8628, Japan.
Chem Commun (Camb). 2005 Oct 28(40):5065-7. doi: 10.1039/b511171d. Epub 2005 Sep 21.
The aromatic C-H silylation of five-membered heteroarenes with 1,2-di-tert-butyl-1,1,2,2-tetrafluorodisilane regioselectively proceeded at 120 degrees C in octane in the presence of a catalytic amount of iridium(I) complexes generated from 1/2[Ir(OMe)(COD)]2 and 2-tert-butyl-1,10-phenanthroline.
在由1/2[Ir(OMe)(COD)]2和2-叔丁基-1,10-菲咯啉生成的催化量铱(I)配合物存在下，五元杂芳烃与1,2-二叔丁基-1,1,2,2-四氟二硅烷的芳香C-H硅基化反应在120℃的辛烷中区域选择性地进行。
