通过钌催化二氢呋喃与α,β-不饱和酯的区域和立体选择性共二聚反应合成2-亚烷基四氢呋喃
Synthesis of 2-alkylidenetetrahydrofurans by Ru-catalyzed regio- and stereoselective codimerization of dihydrofurans with alpha,beta-unsaturated esters.
作者信息
Tsujita Hiroshi, Ura Yasuyuki, Wada Kenji, Kondo Teruyuki, Mitsudo Take-Aki
机构信息
Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto, 615-8510, Japan.
出版信息
Chem Commun (Camb). 2005 Oct 28(40):5100-2. doi: 10.1039/b509578f. Epub 2005 Sep 9.
DOI:10.1039/b509578f
PMID:16220184
Abstract
2-(1-Alkoxycarbonyl)alkylidenetetrahydrofurans were readily synthesized by the codimerization of 2,3- or 2,5-dihydrofurans with alpha,beta-unsaturated esters using a zerovalent Ru catalyst, Ru(cod)(cot), with high regio- and stereoselectivity.
摘要
使用零价钌催化剂Ru(cod)(cot)，通过2,3-或2,5-二氢呋喃与α,β-不饱和酯的共二聚反应，可轻松合成2-(1-烷氧羰基)亚烷基四氢呋喃，具有高区域选择性和立体选择性。
Zotero 插件