Gierczak R F D, Devlin J F, Rudolph D L
Department of Earth Sciences, University of Waterloo, 200 University Avenue West, Waterloo, Ontario N2L 3G1, Canada.
J Contam Hydrol. 2006 Jan 5;82(1-2):75-98. doi: 10.1016/j.jconhyd.2005.09.002. Epub 2005 Oct 21.
Elevated nitrate concentrations within a municipal water supply aquifer led to pilot testing of a field-scale, in situ denitrification technology based on carbon substrate injections. In advance of the pilot test, detailed characterization of the site was undertaken. The aquifer consisted of complex, discontinuous and interstratified silt, sand and gravel units, similar to other well studied aquifers of glaciofluvial origin, 15-40 m deep. Laboratory and field tests, including a conservative tracer test, a pumping test, a borehole flowmeter test, grain-size analysis of drill cuttings and core material, and permeameter testing performed on core samples, were performed on the most productive depth range (27-40 m), and the results were compared. The velocity profiles derived from the tracer tests served as the basis for comparison with other methods. The spatial variation in K, based on grain-size analysis, using the Hazen method, were poorly correlated with the breakthrough data. Trends in relative hydraulic conductivity (K/K(avg)) from permeameter testing compared somewhat better. However, the trends in transient drawdown with depth, measured in multilevel sampling points, corresponded particularly well with those of solute mass flux. Estimates of absolute K, based on standard pumping test analysis of the multilevel drawdown data, were inversely correlated with the tracer test data. The inverse nature of the correlation was attributed to assumptions in the transient drawdown packages that were inconsistent with the variable diffusivities encountered at the scale of the measurements. Collectively, the data showed that despite a relatively low variability in K within the aquifer under study (within a factor of 3), water and solute mass fluxes were concentrated in discrete intervals that could be targeted for later bioremediation.
市政供水含水层中硝酸盐浓度升高,促使对基于碳基质注入的现场规模原位反硝化技术进行了中试。在中试之前,对场地进行了详细的特征描述。该含水层由复杂、不连续且互层的粉砂、砂和砾石单元组成,类似于其他经过充分研究的冰川河流成因的含水层,深度为15 - 40米。在最具生产能力的深度范围(27 - 40米)进行了实验室和现场测试,包括保守示踪剂测试、抽水试验、钻孔流量计测试、钻屑和岩芯材料的粒度分析以及对岩芯样品进行的渗透仪测试,并对结果进行了比较。示踪剂测试得出的流速剖面用作与其他方法比较的基础。基于粒度分析并使用哈森方法得出的K的空间变化与突破数据相关性较差。渗透仪测试得出的相对水力传导率(K/K(avg))趋势的相关性稍好一些。然而,在多级采样点测量的随深度的瞬态水位下降趋势与溶质质量通量趋势特别吻合。基于对多级水位下降数据的标准抽水试验分析得出的绝对K估计值与示踪剂测试数据呈负相关。这种相关性的反比性质归因于瞬态水位下降程序包中的假设与测量尺度上遇到的可变扩散率不一致。总体而言,数据表明,尽管所研究的含水层内K的变异性相对较低(在3倍范围内),但水和溶质质量通量集中在离散区间,这些区间可作为后期生物修复的目标。