两性霉素 E 的 C6-C21 片段的合成。
Synthesis of the C6-C21 segment of amphidinolide E.
作者信息
Marshall James A, Schaaf Gregory, Nolting Andrew
机构信息
Department of Chemistry, University of Virginia, P.O. Box 400319, Charlottesville, Virginia 22904, USA.
出版信息
Org Lett. 2005 Nov 10;7(23):5331-3. doi: 10.1021/ol0523493.
PMID:16268571
Abstract
[reaction: see text] A convergent approach to a C6-C21 segment of the polyketide amphidinolide E has been developed through combination of three subunits by allenylindium bromide-aldehyde addition and Suzuki sp2-sp3 coupling.
摘要
[反应：见正文] 通过溴化烯丙基铟-醛加成反应和铃木sp2-sp3偶联反应将三个亚基结合，已开发出一种合成聚酮类多球壳菌素E的C6-C21片段的汇聚方法。
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