Jiang Hong, Deng Xianming, Sun Xiuli, Tang Yong, Dai Li-Xin
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, 354 Fenglin Lu, Shanghai 200032, China.
J Org Chem. 2005 Nov 25;70(24):10202-5. doi: 10.1021/jo051782n.
[reaction: see text] Alkylidene or arylidene malonates reacted with arsonium allylides to give trans-disubstituted cyclopropane-1,1-dicarboxylates with high stereoselectivity in high yields. The mechanism of the cyclopropanation reactions has also been investigated.
[反应：见正文] 亚烷基或亚芳基丙二酸酯与烯丙基胂叶立德反应，以高立体选择性高产率得到反式二取代环丙烷-1,1-二羧酸酯。还对环丙烷化反应的机理进行了研究。
