Hsieh Lien-Te, Yang Hsi-Hsien, Chen Ho-Wen
Department of Environmental Engineering and Science, National Pingtung University of Science and Technology, Nei Pu 912, Ping Tung 91201,
J Hazard Mater. 2006 Feb 6;128(2-3):106-15. doi: 10.1016/j.jhazmat.2005.08.001. Epub 2005 Nov 18.
This study assessed the concentrations of five volatile organic compounds (VOCs), including BTEX (the acronym for benzene, toluene, ethylbenzene, and xylene) and methyl tertiary-butyl ether (MTBE), in six different industrial park neighborhoods in southern Taiwan, including the Nei-Pu, Ping-Tung, Ping-Nan, Ren-Wu, Lin-Yuan and Nan-Zi industrial parks. The concentrations of MTBE and BTEX ranged from undetectable to 145.6 microg/m3. Average MTBE-BTEX ratios of Nei-Pu, Ping-Tung, Ping-Nan, Ren-Wu, Lin-Yuan and Nan-Zi were (13.4:3.6:4.7:1.0:7.4), (2.9:1.0:1.7:1.3:2.9), (3.0:1.0:2.7:1.0:2.7), (5.2:1.0:8.6:1.7:4.9), (3.1:3.1:2.8:1.0:3.3) and (4.3:1.2:3.6:1.0:3.8), respectively. Moreover, average T/B ratios in Nei-Pu, Ping-Tung, Ping-Nan, Ren-Wu, Lin-Yuan and Nan-Zi were 1.3, 1.7, 2.6, 8.6, 0.9 and 2.9, respectively. High T/B ratio (8.6) in the neighborhood of the Ren-Wu industrial park suggested that the emission of large additional sources of toluene from this industrial park, or the existence of major differences in the auxiliary fuels used. Average X/E ratios in Nei-Pu, Ping-Tung, Ping-Nan, Ren-Wu, Lin-Yuan and Nan-Zi were 7.4, 2.2, 2.7, 2.9, 3.3 and 3.8, respectively. The lower X/E ratio (2.2) in the Ping-Tung neighborhood compared to elsewhere indicates an aged air parcel. Furthermore, principal component analysis also confirmed that the dominant influences in the six different industrial park neighborhoods were related to the emissions of MTBE, benzene and toluene.
本研究评估了台湾南部六个不同工业园区周边地区(包括内埔、屏东、屏南、仁武、林园和楠梓工业园区)五种挥发性有机化合物(VOCs)的浓度,其中包括BTEX(苯、甲苯、乙苯和二甲苯的首字母缩写)和甲基叔丁基醚(MTBE)。MTBE和BTEX的浓度范围从检测不到到145.6微克/立方米。内埔、屏东、屏南、仁武、林园和楠梓的MTBE与BTEX平均比值分别为(13.4:3.6:4.7:1.0:7.4)、(2.9:1.0:1.7:1.3:2.9)、(3.0:1.0:2.7:1.0:2.7)、(5.2:1.0:8.6:1.7:4.9)、(3.1:3.1:2.8:1.0:3.3)和(4.3:1.2:3.6:1.0:3.8)。此外,内埔、屏东、屏南、仁武、林园和楠梓的平均T/B比值分别为1.3、1.7、2.6、8.6、0.9和2.9。仁武工业园区周边地区较高的T/B比值(8.6)表明,该工业园区有大量额外甲苯源排放,或者所使用的辅助燃料存在重大差异。内埔、屏东、屏南、仁武、林园和楠梓的平均X/E比值分别为7.4、2.2、2.7、2.9、3.3和3.8。屏东周边地区的X/E比值(2.2)低于其他地区,表明气团老化。此外,主成分分析也证实,六个不同工业园区周边地区的主要影响因素与MTBE、苯和甲苯的排放有关。