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大气中新兴有机污染物的新进展。

New developments on emerging organic pollutants in the atmosphere.

机构信息

Institute of Atmospheric Pollution Research-National Research Council of Italy (CNR-IIA), Via Salaria km 29.3, 00015 Monterotondo Stazione, RM, Italy.

出版信息

Environ Sci Pollut Res Int. 2012 Jul;19(6):1875-84. doi: 10.1007/s11356-012-0815-2. Epub 2012 Jul 3.

Abstract

BACKGROUND

The continuous progress in analytical techniques has improved the capability of detecting chemicals and recognizing new substances and extended the list of detectable contaminants widespread in all environmental compartments by human activities. Most concern is focused on water contamination by emerging compounds. By contrast, scarce attention is paid to the atmospheric sector, which in most cases represents the pathway of diffusion at local or global scale. Information concerning a list of organic pollutants is provided in this paper.

METHODS

The volatile methyl tert-butyl ether and siloxanes are taken as examples of information insufficient with regard to the potential risk induced by diffusion in the atmosphere. Illicit drugs, whose presence in the air was ascertained although by far unexpected, are considered to stress the needs of investigating not solely the environmental compartments where toxic substances are suspected to display their major influence. Finally, the identification of two recognized emerging contaminants, i.e., tris(2-chloroisopropyl) phosphate and N,N-diethyl-m-toluamide, in aerosols originally run to characterize other target compounds is presented with the purpose of underlining the wide diffusion of the organic emerging contaminants in the environment.

摘要

背景

分析技术的不断进步提高了检测化学品和识别新物质的能力,并扩大了人类活动广泛存在于所有环境介质中的可检测污染物的清单。人们最关注的是新兴化合物对水的污染。相比之下,人们对大气领域关注甚少,而大气在大多数情况下是污染物在局部或全球范围内扩散的途径。本文提供了有关有机污染物清单的信息。

方法

易挥发的甲基叔丁基醚和硅氧烷就是关于扩散在大气中可能引发的潜在风险方面信息不足的例子。尽管出乎意料,但空气中存在的非法药物被认为强调了不仅需要调查那些被怀疑存在毒性物质的环境介质,还需要调查其他环境介质。最后,本文介绍了在最初为了表征其他目标化合物而采集的气溶胶中鉴定出两种公认的新兴污染物,即磷酸三(2-氯异丙基)酯和 N,N-二乙基间甲苯酰胺,以强调有机新兴污染物在环境中的广泛扩散。

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