Mao Yuanbing, Park Tae-Jin, Wong Stanislaus S
Department of Chemistry, State University of New York at Stony Brook, 11794, USA.
Chem Commun (Camb). 2005 Dec 14(46):5721-35. doi: 10.1039/b509960a. Epub 2005 Nov 3.
Nanoscale structures, such as nanoparticles, nanorods, nanowires, nanocubes, and nanotubes, have attracted extensive synthetic attention as a result of their novel size-dependent properties. Ideally, the net result of nanoscale synthesis is the production of structures that achieve monodispersity, stability, and crystallinity with a predictable morphology. Many of the synthetic methods used to attain these goals have been based on principles derived from semiconductor technology, solid state chemistry, and molecular inorganic cluster chemistry. We describe a number of advances that have been made in the reproducible synthesis of various ternary oxide nanomaterials, including alkaline earth metal titanates, alkali metal titanates, bismuth ferrites, ABO(4)-type oxides, as well as miscellaneous classes of ternary metal oxides.
纳米级结构，如纳米颗粒、纳米棒、纳米线、纳米立方体和纳米管，由于其新颖的尺寸依赖性特性而吸引了广泛的合成关注。理想情况下，纳米级合成的最终结果是生产出具有可预测形态的单分散、稳定且结晶的结构。许多用于实现这些目标的合成方法都基于源自半导体技术、固态化学和分子无机簇化学的原理。我们描述了在各种三元氧化物纳米材料的可重复合成方面取得的一些进展，包括碱土金属钛酸盐、碱金属钛酸盐、铋铁氧体、ABO(4)型氧化物以及其他各类三元金属氧化物。
