森田-贝利斯-希尔曼反应中前所未有的反应活性；使用饱和卤代烃对烯酮进行分子内α-烷基化反应。
Unprecedented reactivity in the Morita-Baylis-Hillman reaction; intramolecular alpha-alkylation of enones using saturated alkyl halides.
作者信息
Krafft Marie E, Seibert Kimberly A, Haxell Thomas F N, Hirosawa Chitaru
机构信息
Department of Chemistry and Biochemistry, Florida State University, Tallahassee, 32306-4390, USA.
出版信息
Chem Commun (Camb). 2005 Dec 14(46):5772-4. doi: 10.1039/b512665g. Epub 2005 Nov 4.
DOI:10.1039/b512665g
PMID:16307141
Abstract
sp3 Hybridized electrophiles, never before used in the organomediated Morita-Baylis-Hillman reaction, now facilitate the formation of five- and six-membered enone cycloalkylation products.
摘要
sp3杂化亲电试剂此前从未用于有机介导的森田-贝利斯-希尔曼反应，现在却能促进五元及六元烯酮环烷基化产物的形成。
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