碱促进糖环氧化合物重排为不饱和糖。
Base-promoted rearrangement of sugar epoxides to unsaturated sugars.
作者信息
Wang Yuan, Li Qin, Cheng Shuihong, Wu Yanfen, Guo Dongjie, Fan Qiu-Hua, Wang Xiaofang, Zhang Li-He, Ye Xin-Shan
机构信息
The State Key Laboratory of Natural and Biomimetic Drugs, School of Pharmaceutical Sciences, Peking University, Beijing, 100083, China.
出版信息
Org Lett. 2005 Dec 8;7(25):5577-9. doi: 10.1021/ol052128x.
PMID:16320995
Abstract
[chemical reaction: see text]. A simple and efficient method for rearranging 2,3-anhydro carbohydrates to unsaturated sugars has been developed. The exceptionally mild reaction conditions and high stereoselectivity should make this an attractive method for the preparation of unsaturated carbohydrate derivatives.
摘要
[化学反应：见正文]。已开发出一种将2,3-脱水碳水化合物重排为不饱和糖的简单有效方法。异常温和的反应条件和高立体选择性应使其成为制备不饱和碳水化合物衍生物的一种有吸引力的方法。
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