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Stabilisation of a paramagnetic BH(4-)-bridged dinickel(II) complex by a macrodinucleating hexaaza-dithiophenolate ligand.

作者信息

Journaux Yves, Lozan Vasile, Klingele Julia, Kersting Berthold

机构信息

Laboratoire de Chimie Inorganique et Matériaux Moléculaires Bat F UMR CNRS 7071, case courrier 42, Université Pierre et Marie Curie, 4 place Jussieu, F75252, Paris cedex 05, France.

出版信息

Chem Commun (Camb). 2006 Jan 7(1):83-4. doi: 10.1039/b512744k. Epub 2005 Nov 23.

DOI:10.1039/b512744k
PMID:16353100
Abstract

The first paramagnetic borohydrido-bridged dinuclear nickel(II) complex, [(L)Ni(II)2(mu(1,3)-BH4)]+, stabilised by a sterically demanding hexaaza-dithiophenolate macrocycle, has been obtained by the reaction of [(L)Ni(II)2(micro-ClO4)]+ with N(n)Bu4BH4.

摘要

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