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Molecular recognition and self-assembly special feature: Self-assembled biomimetic [2Fe2S]-hydrogenase-based photocatalyst for molecular hydrogen evolution.分子识别与自组装专题：基于自组装仿生[2Fe2S]氢化酶的光催化剂用于分子氢析出
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本文引用的文献

1
Modeling [Fe-Fe] hydrogenase: evidence for bridging carbonyl and distal iron coordination vacancy in an electrocatalytically competent proton reduction by an iron thiolate assembly that operates through Fe(0)-Fe(II) levels.[铁-铁]氢化酶建模：通过铁硫醇盐组装体进行电催化活性质子还原过程中，羰基桥连和远端铁配位空位的证据，该组装体通过Fe(0)-Fe(II)水平起作用。
J Am Chem Soc. 2007 Sep 12;129(36):11085-92. doi: 10.1021/ja071331f. Epub 2007 Aug 18.
2
Unsaturated, mixed-valence diiron dithiolate model for the H(ox) state of the [FeFe] hydrogenase.用于[FeFe]氢化酶H(ox)状态的不饱和、混合价态二铁二硫醇盐模型。
Angew Chem Int Ed Engl. 2007;46(32):6152-4. doi: 10.1002/anie.200702224.
3
A mixed-valent, Fe(II)Fe(I), diiron complex reproduces the unique rotated state of the [FeFe]hydrogenase active site.一种混合价态的Fe(II)Fe(I)双铁配合物再现了[FeFe]氢化酶活性位点独特的旋转状态。
J Am Chem Soc. 2007 Jun 6;129(22):7008-9. doi: 10.1021/ja071851a. Epub 2007 May 11.
4
A dinuclear Ni(mu-H)Ru complex derived from H2.一种由氢气衍生而来的双核镍（μ-H）钌配合物。
Science. 2007 Apr 27;316(5824):585-7. doi: 10.1126/science.1138751.
5
Evidence for the formation of terminal hydrides by protonation of an asymmetric iron hydrogenase active site mimic.通过不对称铁氢化酶活性位点模拟物的质子化形成末端氢化物的证据。
Inorg Chem. 2007 Apr 30;46(9):3426-8. doi: 10.1021/ic0703124. Epub 2007 Mar 31.
6
A third type of hydrogenase catalyzing H2 activation.第三种催化氢气活化的氢化酶。
Chem Rec. 2007;7(1):37-46. doi: 10.1002/tcr.20111.
7
Stabilisation of a paramagnetic BH(4-)-bridged dinickel(II) complex by a macrodinucleating hexaaza-dithiophenolate ligand.
Chem Commun (Camb). 2006 Jan 7(1):83-4. doi: 10.1039/b512744k. Epub 2005 Nov 23.
8
Characterization of a diferrous terminal hydride mechanistically relevant to the Fe-only hydrogenases.一种与仅含Fe的氢化酶在机制上相关的二价铁末端氢化物的表征。
J Am Chem Soc. 2005 Nov 23;127(46):16012-3. doi: 10.1021/ja055475a.
9
Structural bases for the catalytic mechanism of Ni-containing carbon monoxide dehydrogenases.含镍一氧化碳脱氢酶催化机制的结构基础。
Dalton Trans. 2005 Nov 7(21):3443-50. doi: 10.1039/b508403b. Epub 2005 Sep 23.
10
DFT Investigation of H2 activation by [M(NHPnPr3)('S3')] (M = Ni, Pd). Insight into key factors relevant to the design of hydrogenase functional models.[M(NHPnPr3)('S3')]（M = Ni，Pd）对H2活化的密度泛函理论研究。深入了解与氢化酶功能模型设计相关的关键因素。
J Am Chem Soc. 2005 Sep 28;127(38):13180-9. doi: 10.1021/ja0508424.

Models for the hydrogenases put the focus where it should be--hydrogen.

作者信息

Mealli Carlo, Rauchfuss Thomas B

机构信息

Istituto di Chimica dei Composti Organometallici, ICCOM-CNR, Via Madonna del Piano 10, 50019 Sesto Fiorentino, Firenze, Italy.

出版信息

Angew Chem Int Ed Engl. 2007;46(47):8942-4. doi: 10.1002/anie.200703413.

DOI:10.1002/anie.200703413
PMID:17963205
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2424209/
Abstract
摘要