Zadrazil Ales, Sevcíková Hana
Center for Nonlinear Dynamics of Chemical and Biological Systems, Prague Institute of Chemical Technology, Technická 5, 16628 Prague 6, Czech Republic.
J Chem Phys. 2005 Nov 1;123(17):174509. doi: 10.1063/1.2102809.
The influence of dc electric fields (EFs) on the development of buoyancy-driven instabilities of reaction fronts is investigated experimentally in a modified Hele-Shaw cell for the arsenous acid-iodate system. Assessment of effects of external EFs is made both visually and through dispersion curves. It is shown that density fingering, observed on ascending fronts, is suppressed by the EF if the front propagates towards the positive electrode and is enhanced when the front propagates towards the negative electrode. The stabilizing (destabilizing) effects include slower (faster) development of fingers and the decrease (increase) in their numbers. The descending front, stable under no EF conditions, remains stable when an EF is applied with the positive electrode facing the approaching front. When the descending front faces the negative electrode, the tiny fingerlike structure develops after quite a long time.