豇豆象（Callosobruchus maculatus）交配释放信息素的一种成分——2,6 - 二甲基辛烷 - 1,8 - 二酸四种立体异构体的合成。
Synthesis of the four stereoisomers of 2,6-dimethyloctane-1,8-dioic acid, a component of the copulation release pheromone of the cowpea weevil, Callosobruchus maculatus.
作者信息
Nakai Tomonori, Yajima Arata, Akasaka Kazuaki, Kaihoku Takayuki, Ohtaki Miki, Nukada Tomoo, Ohrui Hiroshi, Yabuta Goro
机构信息
Department of Fermentation Science, Faculty of Applied Biological Science, Tokyo University of Agriculture, Japan.
出版信息
Biosci Biotechnol Biochem. 2005 Dec;69(12):2401-8. doi: 10.1271/bbb.69.2401.
A diastereomeric mixture and the four stereoisomers of 2,6-dimethyloctane-1,8-dioic acid (2), a copulation release pheromone of the cowpea weevil, Callosobruchus maculatus, were synthesized. The stereoisomeric purities of the four synthetic isomers of 2 were determined by the HPLC analyses of their bis-2-(2,3-anthracenedicarboximide)-1-cyclohexyl esters.
合成了2,6 - 二甲基辛烷 - 1,8 - 二酸（2）的非对映异构体混合物及其四种立体异构体，2,6 - 二甲基辛烷 - 1,8 - 二酸（2）是豇豆象（Callosobruchus maculatus）的一种交配释放信息素。通过对其双 - 2 -（2,3 - 蒽二羧酰亚胺）- 1 - 环己酯进行高效液相色谱分析，确定了2的四种合成异构体的立体化学纯度。
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