Pop Eric, Mann David, Wang Qian, Goodson Kenneth, Dai Hongjie
Department of Chemistry and Laboratory for Advanced Materials, Stanford University, California 94305, USA.
Nano Lett. 2006 Jan;6(1):96-100. doi: 10.1021/nl052145f.
The thermal properties of a suspended metallic single-wall carbon nanotube (SWNT) are extracted from its high-bias (I-V) electrical characteristics over the 300-800 K temperature range, achieved by Joule self-heating. The thermal conductance is approximately 2.4 nW/K, and the thermal conductivity is nearly 3500 Wm(-1)K(-1) at room temperature for a SWNT of length 2.6 mum and diameter 1.7 nm. A subtle decrease in thermal conductivity steeper than 1/T is observed at the upper end of the temperature range, which is attributed to second-order three-phonon scattering between two acoustic modes and one optical mode. We discuss sources of uncertainty and propose a simple analytical model for the SWNT thermal conductivity including length and temperature dependence.
通过焦耳自热实现了在300 - 800K温度范围内,从悬浮金属单壁碳纳米管(SWNT)的高偏置(I - V)电学特性中提取其热性质。对于长度为2.6μm、直径为1.7nm的SWNT,在室温下其热导约为2.4nW/K,热导率接近3500Wm⁻¹K⁻¹。在温度范围上限处观察到热导率有比1/T更陡的细微下降,这归因于两个声学模式和一个光学模式之间的二阶三声子散射。我们讨论了不确定性来源,并提出了一个包含长度和温度依赖性的SWNT热导率简单分析模型。