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室温以上单个单壁碳纳米管的热导率。

Thermal conductance of an individual single-wall carbon nanotube above room temperature.

作者信息

Pop Eric, Mann David, Wang Qian, Goodson Kenneth, Dai Hongjie

机构信息

Department of Chemistry and Laboratory for Advanced Materials, Stanford University, California 94305, USA.

出版信息

Nano Lett. 2006 Jan;6(1):96-100. doi: 10.1021/nl052145f.

Abstract

The thermal properties of a suspended metallic single-wall carbon nanotube (SWNT) are extracted from its high-bias (I-V) electrical characteristics over the 300-800 K temperature range, achieved by Joule self-heating. The thermal conductance is approximately 2.4 nW/K, and the thermal conductivity is nearly 3500 Wm(-1)K(-1) at room temperature for a SWNT of length 2.6 mum and diameter 1.7 nm. A subtle decrease in thermal conductivity steeper than 1/T is observed at the upper end of the temperature range, which is attributed to second-order three-phonon scattering between two acoustic modes and one optical mode. We discuss sources of uncertainty and propose a simple analytical model for the SWNT thermal conductivity including length and temperature dependence.

摘要

通过焦耳自热实现了在300 - 800K温度范围内,从悬浮金属单壁碳纳米管(SWNT)的高偏置(I - V)电学特性中提取其热性质。对于长度为2.6μm、直径为1.7nm的SWNT,在室温下其热导约为2.4nW/K,热导率接近3500Wm⁻¹K⁻¹。在温度范围上限处观察到热导率有比1/T更陡的细微下降,这归因于两个声学模式和一个光学模式之间的二阶三声子散射。我们讨论了不确定性来源,并提出了一个包含长度和温度依赖性的SWNT热导率简单分析模型。

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