Fujii Motoo, Zhang Xing, Xie Huaqing, Ago Hiroki, Takahashi Koji, Ikuta Tatsuya, Abe Hidekazu, Shimizu Tetsuo
Institute for Materials Chemistry and Engineering, Kyushu University, Kasuga 816-8580, Japan.
Phys Rev Lett. 2005 Aug 5;95(6):065502. doi: 10.1103/PhysRevLett.95.065502. Epub 2005 Aug 2.
Although the thermal properties of millimeter-sized carbon nanotube mats and packed carbon nanofibers have been readily measured, measurements for a single nanotube are extremely difficult. Here, we report a novel method that can reliably measure the thermal conductivity of a single carbon nanotube using a suspended sample-attached T-type nanosensor. Our experimental results show that the thermal conductivity of a carbon nanotube at room temperature increases as its diameter decreases, and exceeds 2000 W/mK for a diameter of 9.8 nm. The temperature dependence of the thermal conductivity for a carbon nanotube with a diameter of 16.1 nm appears to have an asymptote near 320 K. The present method is, in principle, applicable to any kind of a single nanofiber, nanowire, and even single-walled carbon nanotube.
尽管毫米尺寸的碳纳米管垫和填充碳纳米纤维的热性能已易于测量,但对单个纳米管的测量却极其困难。在此,我们报告一种新颖的方法,该方法可使用附着有悬浮样品的T型纳米传感器可靠地测量单个碳纳米管的热导率。我们的实验结果表明,室温下碳纳米管的热导率随其直径减小而增加,对于直径为9.8 nm的碳纳米管,其热导率超过2000 W/mK。直径为16.1 nm的碳纳米管的热导率与温度的关系在320 K附近似乎有一条渐近线。本方法原则上适用于任何种类的单个纳米纤维、纳米线,甚至单壁碳纳米管。