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Screening of a supramolecular catalyst library in the search for selective catalysts for the asymmetric hydrogenation of a difficult enamide substrate.

作者信息

Jiang Xiao-Bin, Lefort Laurent, Goudriaan P Elsbeth, de Vries André H M, van Leeuwen Piet W N M, de Vries Johannes G, Reek Joost N H

机构信息

Homogeneous Catalysis van't Hoff Institute for Molecular Sciences, University of Amsterdam, Nieuwe Achtergracht 166, 1018 WV Amsterdam, The Netherlands.

出版信息

Angew Chem Int Ed Engl. 2006 Feb 13;45(8):1223-7. doi: 10.1002/anie.200503663.

DOI:10.1002/anie.200503663
PMID:16411269
Abstract
摘要

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Screening of a supramolecular catalyst library in the search for selective catalysts for the asymmetric hydrogenation of a difficult enamide substrate.筛选超分子催化剂库以寻找用于难烯酰胺底物不对称氢化的选择性催化剂。
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Asymmetric enamide hydrogenation using phosphinite thioglycosides: synthesis of D- and L-aminoesters using D-sugars as catalyst precursors.使用亚磷酸酯硫代糖苷的不对称烯酰胺氢化反应:以D-糖为催化剂前体合成D-和L-氨基酸酯。
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The hydrogenation/transfer hydrogenation network: asymmetric hydrogenation of ketones with chiral eta6-arene/N-Tosylethylenediamine-ruthenium(II) catalysts.氢化/转移氢化网络:使用手性η6-芳烃/N-对甲苯磺酰基乙二胺-钌(II)催化剂对酮进行不对称氢化
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