Bryce David L, Sward Gregory D
Department of Chemistry, University of Ottawa, Ottawa, Ontario K1N 6N5, Canada.
Magn Reson Chem. 2006 Apr;44(4):409-50. doi: 10.1002/mrc.1741.
A thorough review of 35/37Cl, 79/81Br, and 127I solid-state nuclear magnetic resonance (SSNMR) data is presented. Isotropic chemical shifts (CS), quadrupolar coupling constants, and other available information on the magnitude and orientation of the CS and electric field gradient (EFG) tensors for chlorine, bromine, and iodine in diverse chemical compounds is tabulated on the basis of over 200 references. Our coverage is through July 2005. Special emphasis is placed on the information available from the study of powdered diamagnetic solids in high magnetic fields. Our survey indicates a recent notable increase in the number of applications of solid-state quadrupolar halogen NMR, particularly 35Cl NMR, as high magnetic fields have become more widely available to solid-state NMR spectroscopists. We conclude with an assessment of possible future directions for research involving 35/37Cl, 79/81Br, and 127I solid-state NMR spectroscopy.
本文对³⁵/³⁷Cl、⁷⁹/⁸¹Br和¹²⁷I的固态核磁共振（SSNMR）数据进行了全面综述。基于200多篇参考文献，列出了各化合物中氯、溴和碘的各向同性化学位移（CS）、四极耦合常数以及其他有关CS和电场梯度（EFG）张量大小和方向的可用信息。我们的覆盖范围截至2005年7月。特别强调了在高磁场下对粉末状抗磁性固体研究中获得的信息。我们的调查表明，随着高磁场在固态核磁共振光谱学家中更广泛地可用，固态四极卤核核磁共振，特别是³⁵Cl NMR的应用数量最近显著增加。我们最后评估了涉及³⁵/³⁷Cl、⁷⁹/⁸¹Br和¹²⁷I固态核磁共振光谱学研究未来可能的方向。
