Larrosa Igor, Romea Pedro, Urpí Fèlix
Departament de Química Orgànica, Universitat de Barcelona, Martí i Franqués 1-11, 08028 Barcelona, Catalonia, Spain.
Org Lett. 2006 Feb 2;8(3):527-30. doi: 10.1021/ol052900w.
[structure: see text]. A convergent and module-based strategy for the asymmetric synthesis of the western hemisphere (C1-C17 fragment) of salinomycin has been devised. This new synthetic approach relies on highly stereoselective C-glycosidation and aldol processes.
[结构：见正文]。已设计出一种用于盐霉素西半球（C1 - C17片段）不对称合成的收敛且基于模块的策略。这种新的合成方法依赖于高度立体选择性的C - 糖苷化和羟醛反应过程。
