铕（III）和铽（III）与异位配体形成的新型配合物的发光性质
Luminescense properties of new complexes of Eu(III) and Tb(III) with heterotopic ligands.
作者信息
Patroniak Violetta, Hnatejko Zbigniew, Grochowska Agnieszka M, Stefankiewicz Artur R
机构信息
Faculty of Chemistry, Adam Mickiewicz University, Grunwaldzka 6, 60780 Poznań, Poland.
出版信息
Spectrochim Acta A Mol Biomol Spectrosc. 2006 Jul;64(4):830-4. doi: 10.1016/j.saa.2005.08.011. Epub 2006 Jan 27.
As a result of coordination between ligands L and L' and europium(III) and terbium(III) ions, the new architectures were formed. The formulae of the complexes have been assigned on the basis of the spectroscopic data in solution and microanalyses. The europium complexes show excellent luminescence properties with high quantum yield (1b-Eu(3)L(2)) and effective intramolecular energy transfer from the ligand to the Eu(III) ions.
由于配体L和L'与铕（III）和铽（III）离子之间的配位作用，形成了新的结构。配合物的化学式已根据溶液中的光谱数据和微量分析确定。铕配合物表现出优异的发光性能，具有高量子产率（1b-Eu(3)L(2)）以及从配体到Eu(III)离子的有效分子内能量转移。
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