一种分子风车状多铜（I）簇合物，即[(L(S-))6Cu(I)13(S2-)2]3+，含有μ4-硫桥基、μ3-硫醇盐和氮配体。
A molecular pinwheel multicopper(I) cluster, [(L(S-))6Cu(I)13(S2-)2]3+ with mu4-sulfido, mu3-thiolato and nitrogen ligands.
作者信息
Lee Yunho, Sarjeant Amy A Narducci, Karlin Kenneth D
机构信息
Department of Chemistry, John Hopkins University, 3400 North Charles Street, Baltimore, MD 21218, USA.
出版信息
Chem Commun (Camb). 2006 Feb 14(6):621-3. doi: 10.1039/b513768c. Epub 2005 Dec 21.
DOI:10.1039/b513768c
PMID:16446829
Abstract
A copper(I) complex with new N2S thiol ligand transforms to a multicopper(I) cluster, [(L(S-))6Cu(I)13(S2-)2]3+ (1); its X-ray structure exhibiting mu4-sulfido and mu3-thiolato coordination is presented and compared to other cuprous thiolato/sulfido clusters including that observed in the copper enzyme nitrous oxide reductase.
摘要
一种与新型N2S硫醇配体形成的铜（I）配合物转变为多铜（I）簇合物[(L(S-))6Cu(I)13(S2-)2]3+（1）；给出了其具有μ4-硫桥和μ3-硫醇配位的X射线结构，并与其他硫醇铜/硫桥簇合物进行了比较，包括在铜酶一氧化二氮还原酶中观察到的簇合物。
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