Corbi Pedro P, Massabni Antonio C
Departamento de Química Geral e Inorgânica, Instituto de Química-UNESP, Rua Prof. Francisco Degni s/n, CP 355, CEP 14801-970, Araraquara, SP, Brazil.
Spectrochim Acta A Mol Biomol Spectrosc. 2006 May 15;64(2):418-9. doi: 10.1016/j.saa.2005.07.039. Epub 2006 Feb 2.
1H-15N 2D NMR data for S-allyl-L-cysteine (deoxyalliin) and for bis(S-allyl-L-cysteinate)palladium(II) complex are presented in this manuscript. Large upfield 15N NMR shift of the amine nitrogen in the spectrum of the complex when compared to the spectrum of the ligand shows clearly coordination of S-allyl-L-cysteine, in the anion form, to palladium(II) through the NH2 group.
本手稿展示了S-烯丙基-L-半胱氨酸（脱氧蒜氨酸）和双（S-烯丙基-L-半胱氨酸）钯（II）配合物的1H-15N二维核磁共振数据。与配体的光谱相比，配合物光谱中胺氮的15N核磁共振信号有很大的高场位移，这清楚地表明阴离子形式的S-烯丙基-L-半胱氨酸通过NH2基团与钯（II）配位。
