用于烯烃环氧化的负载型金属卟啉催化剂。

Supported metalloporphyrin catalysts for alkene epoxidation.

作者信息

Brulé Emilie, de Miguel Yolanda R

机构信息

Université Pierre et Marie Curie, Paris VI, Laboratoire de synthèse organique et organométallique, Tour 44-45, 1erétage, 4 Place Jussieu, 75252, Paris Cedex 05, France.

出版信息

Org Biomol Chem. 2006 Feb 21;4(4):599-609. doi: 10.1039/b509985d. Epub 2005 Dec 20.

DOI:10.1039/b509985d

PMID:16467931

Abstract

This review is devoted to the recent advances in the preparation of immobilised metalloporphyrins and their use as heterogeneous catalysts for alkene epoxidation. The wide range of supports, nature of attachments, and metalloporphyrins that have been reported is detailed and a comparison is made between the activities of the resulting catalysts in the epoxidation of different alkenes. The important issue of recyclability of the metalloporphyrins is also covered.

摘要

本综述致力于固定化金属卟啉制备的最新进展及其作为烯烃环氧化多相催化剂的应用。详细介绍了已报道的广泛的载体、连接方式和金属卟啉，并对所得催化剂在不同烯烃环氧化中的活性进行了比较。还涵盖了金属卟啉可回收性这一重要问题。