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耗散(动态)自组装的原理与实现

Principles and implementations of dissipative (dynamic) self-assembly.

作者信息

Fialkowski Marcin, Bishop Kyle J M, Klajn Rafal, Smoukov Stoyan K, Campbell Christopher J, Grzybowski Bartosz A

机构信息

Department of Chemical and Biological Engineering, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, USA.

出版信息

J Phys Chem B. 2006 Feb 16;110(6):2482-96. doi: 10.1021/jp054153q.

Abstract

Dynamic self-assembly (DySA) processes occurring outside of thermodynamic equilibrium underlie many forms of adaptive and intelligent behaviors in natural systems. Relatively little, however, is known about the principles that govern DySA and the ways in which it can be extended to artificial ensembles. This article discusses recent advances in both the theory and the practice of nonequilibrium self-assembly. It is argued that a union of ideas from thermodynamics and dynamic systems' theory can provide a general description of DySA. In parallel, heuristic design rules can be used to construct DySA systems of increasing complexities based on a variety of suitable interactions/potentials on length scales from nanoscopic to macroscopic. Applications of these rules to magnetohydrodynamic DySA are also discussed.

摘要

发生在热力学平衡之外的动态自组装(DySA)过程是自然系统中多种形式的适应性和智能行为的基础。然而,对于支配DySA的原理以及将其扩展到人工集合体的方式,我们所知相对较少。本文讨论了非平衡自组装理论和实践方面的最新进展。有人认为,将热力学和动态系统理论的思想结合起来,可以对DySA进行一般性描述。同时,可以利用启发式设计规则,基于从纳米尺度到宏观尺度的各种合适相互作用/势,构建复杂度不断增加的DySA系统。还讨论了这些规则在磁流体动力学DySA中的应用。

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