Coles Martyn P
Department of Chemistry, University of Sussex, Falmer, Brighton, UKBN1 9QJ.
Dalton Trans. 2006 Feb 28(8):985-1001. doi: 10.1039/b515490a. Epub 2006 Jan 11.
The aim of this perspective is to highlight the continued development and application of amidines and guanidines as neutral, N-based donor ligands in coordination chemistry. From a sporadic interest dating back to the 1980s, work on these two closely related classes of compounds has steadily grown, with examples of evermore sophisticated substitution about the common ligand framework being developed to address specific problems in a number of fields of chemistry. These compounds have shown varied coordination modes at metals from across the periodic table, and examples of their application in a number of catalytic processes are emerging as the field matures.
本文的目的是突出脒类和胍类作为配位化学中基于氮的中性供体配体的持续发展及应用。自20世纪80年代的零星研究兴趣以来，针对这两类密切相关化合物的研究稳步增长，围绕常见配体骨架开发出越来越复杂的取代基实例，以解决多个化学领域的特定问题。这些化合物在整个周期表中的金属上表现出多样的配位模式，随着该领域的成熟，它们在一些催化过程中的应用实例也不断涌现。
