Minakata Satoshi, Yoneda Yoshimi, Oderaotoshi Yoji, Komatsu Mitsuo
Department of Applied Chemistry, Center for Atomic and Molecular Technologies, Graduate School of Engineering, Osaka University, Yamadaoka 2-1, Suita, Osaka 565-0871, Japan.
Org Lett. 2006 Mar 2;8(5):967-9. doi: 10.1021/ol0600178.
A new synthetic procedure for the aminochlorination of olefins for the synthesis of vicinal chloroamine derivatives using a combination of Chloramine-T and carbon dioxide is described. The method can be applied to a variety of olefins, including an electron-sufficient olefin and a conjugated diene.
描述了一种使用氯胺 -T 和二氧化碳的组合进行烯烃氨氯化以合成邻氯胺衍生物的新合成方法。该方法可应用于多种烯烃,包括富电子烯烃和共轭二烯。