在“五步一锅法反应”中生成的咪唑并菲啶合成子的发现，该反应可导向具有新型物理性质的新杂环化合物家族。
Discovery of an imidazo-phenanthridine synthon produced in a 'five-step one-pot reaction' leading to a new family of heterocycles with novel physical properties.
作者信息
Parenty Alexis D C, Guthrie Kevin M, Song Yu-Fei, Smith Louise V, Burkholder Eric, Cronin Leroy
机构信息
WestCHEM, University of Glasgow, Department of Chemistry, Glasgow, UK G12 8QQ.
出版信息
Chem Commun (Camb). 2006 Mar 21(11):1194-6. doi: 10.1039/b517117b. Epub 2006 Jan 19.
DOI:10.1039/b517117b
PMID:16518488
Abstract
A new class of heterocyclic aromatic cation with novel physical properties has been constructed by an unprecedented reaction pathway that proceeds via five spontaneous steps to yield a 'synthon' that can be further derivatised by a final nucleophilic substitution step.
摘要
通过一条前所未有的反应途径构建了一类具有新颖物理性质的杂环芳香阳离子，该途径通过五个自发步骤生成一个“合成子”，该合成子可通过最后的亲核取代步骤进一步衍生化。
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