Lin Mau-Chin, Lin Sheng-Chieh, Lee Tzu-Hsin, Huang Her-Hsiung
Department of Dental Laboratory Technology, Central Taiwan University of Science and Technology, Taichung, Taiwan.
Angle Orthod. 2006 Mar;76(2):322-9. doi: 10.1043/0003-3219(2006)076[0322:SAACRO]2.0.CO;2.
The purpose of this study was to investigate the variation in corrosion resistance of commercial stainless steel (SS) brackets with different brands and types for the same application, using the electrochemical technique. The linear polarization test was used to evaluate the corrosion resistance, in terms of polarization resistance (Rp), of as-received commercial SS brackets in acidic artificial saliva. A two-way analysis of variance was used to analyze the Rp with the factors of brand and type. A scanning electron microscope and an atomic force microscope were used to analyze the surface morphology and roughness, respectively. The X-ray photoelectron spectroscopy was used to identify the chemical composition of the passive film on SS brackets. Results showed that different brands of SS brackets had a statistically significant difference in Rp (P < .0001), whereas there was no statistical difference between the bracket types ("Roth" and standard) (P = .27). Different surface topography, including surface roughness and defect, was present among the tested SS brackets. The same passive film structure, containing Cr2O3/Fe2O3 with small amounts of NiO, was observed on all SS brackets. The surface topography of the commercial SS brackets with identical surface passive film structure did not correspond with the difference in corrosion resistance.
本研究的目的是使用电化学技术,研究相同用途下不同品牌和类型的商用不锈钢(SS)托槽的耐腐蚀性变化。采用线性极化试验,根据极化电阻(Rp)评估所接收的商用SS托槽在酸性人工唾液中的耐腐蚀性。使用双向方差分析来分析品牌和类型因素对Rp的影响。分别使用扫描电子显微镜和原子力显微镜分析表面形貌和粗糙度。采用X射线光电子能谱法鉴定SS托槽上钝化膜的化学成分。结果表明,不同品牌的SS托槽在Rp上存在统计学显著差异(P <.0001),而托槽类型(“Roth”型和标准型)之间无统计学差异(P = 0.27)。在测试的SS托槽中存在不同的表面形貌,包括表面粗糙度和缺陷。在所有SS托槽上均观察到相同的钝化膜结构,其含有少量NiO的Cr2O3/Fe2O3。具有相同表面钝化膜结构的商用SS托槽的表面形貌与耐腐蚀性差异不对应。