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用于组装具有超大空腔的类沸石金属有机框架(ZMOF)的分子构建块方法。

Molecular building blocks approach to the assembly of zeolite-like metal-organic frameworks (ZMOFs) with extra-large cavities.

作者信息

Liu Yunling, Kravtsov Victor Ch, Larsen Randy, Eddaoudi Mohamed

机构信息

Department of Chemistry, University of South Florida, 4202 E. Fowler Ave. (SCA400), Tampa, FL 33620, USA.

出版信息

Chem Commun (Camb). 2006 Apr 14(14):1488-90. doi: 10.1039/b600188m. Epub 2006 Feb 2.

DOI:10.1039/b600188m
PMID:16575436
Abstract

Two novel porous anionic zeolite-like metal-organic frameworks, rho-ZMOF and sod-ZMOF, have been synthesized by metal-ligand-directed assembly of rigid and directional tetrahedral building units, InN4 synthesized in situ, and doubly deprotonated bis(bidentate) imidazoledicarboxylic acid ligands (HImDC) in the presence of different structure directing agents (SDAs).

摘要

通过原位合成的刚性定向四面体结构单元InN₄以及双去质子化的双(双齿)咪唑二羧酸配体(HImDC),在不同结构导向剂(SDA)存在的情况下,通过金属 - 配体定向组装合成了两种新型多孔阴离子类沸石金属有机框架,即rho-ZMOF和sod-ZMOF。

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