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探索类沸石金属有机框架：关于嘧啶羧酸酯双螯合桥连配体

Quest for zeolite-like metal-organic frameworks: on pyrimidinecarboxylate bis-chelating bridging ligands.

作者信息

Sava Dorina F, Kravtsov Victor Ch, Nouar Farid, Wojtas Lukasz, Eubank Jarrod F, Eddaoudi Mohamed

机构信息

Department of Chemistry, University of South Florida, 4202 East Fowler Avenue (CHE 205), Tampa, Florida 33620, USA.

出版信息

J Am Chem Soc. 2008 Mar 26;130(12):3768-70. doi: 10.1021/ja710616j. Epub 2008 Feb 29.

DOI:10.1021/ja710616j
PMID:18307350
Abstract

Two novel porous zeolitelike metal-organic frameworks (ZMOFs) were constructed via the single metal ion-based molecular building block approach from rigid and directional tetrahedral building units and pyrimidinecarboxylate bridging ligands; their ion exchange and hydrogen sorption properties were evaluated.

摘要

通过基于单金属离子的分子构建块方法，利用刚性且具有方向性的四面体构建单元和嘧啶羧酸酯桥连配体，构建了两种新型的类沸石多孔金属有机骨架材料（ZMOFs）；并对它们的离子交换和氢吸附性能进行了评估。

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