Huo Shouquan, Deaton Joseph C, Rajeswaran Manju, Lenhart William C
Research & Development, Eastman Kodak Company, 1999 Lake Avenue, Rochester, New York 14650-2103, USA.
Inorg Chem. 2006 Apr 17;45(8):3155-7. doi: 10.1021/ic060089v.
A highly efficient and general method based on transmetalation with an organozinc reagent is developed for selective preparation of homo- and heteroleptic meridional tris-cyclometalated iridium complexes. The molecular structure of mer-Ir(1-piq)2(ppy) (2) has been determined by a single-crystal X-ray diffraction analysis. The emission properties of a series of meridional complexes are reported.
开发了一种基于与有机锌试剂进行金属转移反应的高效通用方法，用于选择性制备均配和异配的经式三芳基环金属化铱配合物。通过单晶X射线衍射分析确定了经式-Ir(1-皮考林酸)₂(2-苯基吡啶)（2）的分子结构。报道了一系列经式配合物的发光性质。
