Jarzyńska Maria
Technikum Kształtowania Srodowiska, Piotrków Trybunalski.
Polim Med. 2005;35(4):19-24.
In the paper original manier of derivation of practical transport Kedem-Katchalsky equations (K-K) describing fluxes: volume of solute (Jv) and dissolved substance (Js) for nonelectrolyte, evoked by simultaneous action of direct oriented hydrostatic (deltap) and osmotic (deltaII) pressures of nonelectrolytic solutions was presented. Mathematic expressions describing oefficients characterizing permeability of the membrane: omegadeltaII and omegadeltap, manners of their derivationand their physical interpretation were presented. Equation describing coefficient LD was also derived. Suggested manier of derivation makes K-K equations easier to interpret.
本文介绍了实际传输的 Kedem-Katchalsky 方程(K-K)的原始推导方式,该方程描述了非电解质溶液中溶质体积通量(Jv)和溶解物质通量(Js),它们是由非电解质溶液的直接定向静水压力(deltap)和渗透压(deltaII)的同时作用引起的。给出了描述膜渗透率特征系数的数学表达式:omegadeltaII 和 omegadeltap,它们的推导方式及其物理解释。还推导了描述系数 LD 的方程。所建议的推导方式使 K-K 方程更易于解释。