使用聚甲基氢硅氧烷（PMHS）和催化量的三（五氟苯基）硼（B(C6F5)3）进行的简便且化学选择性共轭还原反应。
A facile and chemoselective conjugate reduction using polymethylhydrosiloxane (PMHS) and catalytic B(C6F5)3.
作者信息
Chandrasekhar Srivari, Chandrashekar Gudise, Reddy Marepally Srinivasa, Srihari Pabbaraja
机构信息
Organic Division-1, Indian Institute of Chemical Technology, Hyderabad, India.
出版信息
Org Biomol Chem. 2006 May 7;4(9):1650-2. doi: 10.1039/b603610b. Epub 2006 Mar 29.
DOI:10.1039/b603610b
PMID:16633555
Abstract
A highly chemoselective conjugate reduction of electron-deficient Michael acceptors, including alpha,beta-unsaturated ketones, carboxylic esters, nitriles and nitro compounds with PMHS in the presence of catalytic B(C6F5)3 is described.
摘要
本文描述了在催化量的三（五氟苯基）硼[B(C6F5)3]存在下，聚甲基氢硅氧烷（PMHS）对缺电子迈克尔受体（包括α,β-不饱和酮、羧酸酯、腈和硝基化合物）进行的高化学选择性共轭还原反应。
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