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Three novel silver complexes with ligand-unsupported argentophilic interactions and their luminescent properties.

作者信息

Liu Xi, Guo Guo-Cong, Fu Ming-Lai, Liu Xue-Hui, Wang Ming-Sheng, Huang Jin-Shun

机构信息

State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, People's Republic of China.

出版信息

Inorg Chem. 2006 May 1;45(9):3679-85. doi: 10.1021/ic0601539.

DOI:10.1021/ic0601539
PMID:16634601
Abstract

Three novel silver complexes, namely, [Ag5(CN)5(bipy)2]n (1) with a 1-D to 3-D architecture constructed through ligand-unsupported argentophilic interactions, [Ag5(SCN)4(CN)(bipy)2]n (2) with a 2-D interesting topology formed by cyanide groups linking [Ag5(SCN)4(bipy)2]n(n+) cationic columns, and [(Me4N)Ag3(CN)4]n (3) with 3-fold-interpenetrated 3-D 3-connected (10, 3)-g nets, have been solvothermally synthesized, and all exhibit efficient luminescence.

摘要

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