锂催化的简单末端烯烃自由基聚合反应。
Li+-catalyzed radical polymerization of simple terminal alkenes.
作者信息
Vyakaranam Kamesh, Barbour Josiah B, Michl Josef
机构信息
Department of Chemistry and Biochemistry, University of Colorado, Boulder, Colorado 80309-0215, USA.
出版信息
J Am Chem Soc. 2006 May 3;128(17):5610-1. doi: 10.1021/ja060087+.
PMID:16637608
Abstract
Solutions of Li+ salts of highly alkylated derivatives of the monocarbadodecaborate anion in 1,2-dichloroethane catalyze the radical polymerization of simple terminal alkenes, dienes, and alkynes under ambient conditions, initiated by azoisobutyronitrile, di-tert-butyl peroxide, or atmospheric air.
摘要
单碳十二硼阴离子的高烷基化衍生物的锂盐在1,2 - 二氯乙烷中的溶液，在偶氮异丁腈、二叔丁基过氧化物或大气中的氧气引发下，能在环境条件下催化简单端烯烃、二烯烃和炔烃的自由基聚合反应。
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