一种间隔配体N,N'-双(2-吡啶基)-2,6-吡啶二甲酰胺的三核镧系元素配合物：光谱研究
Trinuclear lanthanide complexes of a compartmental ligand N,N'-bis(2-pyridinyl)-2,6-pyridinedicarboxamide: a spectroscopic investigation.
作者信息
Gudasi Kalagouda B, Shenoy Rashmi V, Vadavi Ramesh S, Patil Siddappa A
机构信息
Department of Chemistry, Karnatak University, Dharwad 580003, India.
出版信息
Spectrochim Acta A Mol Biomol Spectrosc. 2006 Nov;65(3-4):598-604. doi: 10.1016/j.saa.2005.12.017. Epub 2006 Apr 27.
Trinuclear lanthanide complexes of the formula [Ln(3)(PPDA)(NO(3))(6)(H(2)O)(2)].NO(3).2H(2)O where Ln=La(III), Pr(III), Sm(III), Nd(III), Eu(III) Gd(III) Tb(III), Dy(III) and Y(III); H(2)PPDA=N,N'-bis(2-pyridinyl)-2,6-pyridinedicarboxamide, have been isolated. The complexes were characterized by elemental analyses, conductivity measurements, magnetic susceptibility measurements and spectral (IR, NMR, UV-vis, fluorescence, FAB and EPR) and thermal studies.
已分离出通式为[Ln(3)(PPDA)(NO(3))(6)(H(2)O)(2)].NO(3).2H(2)O的三核镧系元素配合物，其中Ln = La(III)、Pr(III)、Sm(III)、Nd(III)、Eu(III)、Gd(III)、Tb(III)、Dy(III)和Y(III)；H(2)PPDA = N,N'-双(2-吡啶基)-2,6-吡啶二甲酰胺。通过元素分析、电导率测量、磁化率测量以及光谱（红外、核磁共振、紫外可见、荧光、快原子轰击和电子顺磁共振）和热学研究对这些配合物进行了表征。
Zotero 插件