通过氧杂降冰片烯方法合成2-氨基环己烷羧酸的3-羟基、3,4-二羟基和3,4,5-三羟基衍生物。
The oxanorbornene approach to 3-hydroxy, 3,4-dihydroxy and 3,4,5-trihydroxy derivatives of 2-aminocyclohexanecarboxylic acid.
作者信息
Masesane Ishmael B, Batsanov Andrei S, Howard Judith A K, Mondal Raju, Steel Patrick G
机构信息
Department of Chemistry, University of Durham, South Road, Durham, DH1 3LE, UK.
出版信息
Beilstein J Org Chem. 2006 May 4;2:9. doi: 10.1186/1860-5397-2-9.
Abstract
The nitro oxanorbornene adduct derived from the Diels-Alder reaction of ethyl (E)-3-nitroacrylate and furan provides a versatile template for the stereoselective synthesis of hydroxylated derivatives of 2-aminocyclohexanecarboxylic acid (ACHC).
摘要
由（E）-3-硝基丙烯酸乙酯与呋喃的狄尔斯-阿尔德反应得到的硝基氧杂降冰片烯加合物为2-氨基环己烷羧酸（ACHC）羟基化衍生物的立体选择性合成提供了一个通用模板。
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