Ozaki M, Suzuki M, Itoh K, Wakumoto S
Showa University School of Dentistry, Japan.
Dent Mater J. 1991 Dec;10(2):105-20. doi: 10.4012/dmj.10.105.
The possible chemical interaction between synthetic hydroxyapatite or bovine enamel and a functional monomer of 4-methacryloxyethyl trimellitic acid (4-MET) diluted in methyl methacrylate (MMA) was examined by measuring the Raman spectra. It was concluded that the carboxyl group of 4-MET reacted with the calcium in the substrate to form a salt that was detected by the Raman band at around 1,380 cm-1. However, formation of the salt on the surface of the hydroxyapatite (HAP) with the carboxyl group, and polymerization of the 4-MET in the methacryl group near the surface were mutually exclusive reactions for the same 4-MET molecule.
通过测量拉曼光谱，研究了合成羟基磷灰石或牛牙釉质与稀释于甲基丙烯酸甲酯（MMA）中的4-甲基丙烯酰氧乙基偏苯三酸（4-MET）功能单体之间可能的化学相互作用。得出的结论是，4-MET的羧基与底物中的钙发生反应形成一种盐，该盐可通过拉曼谱带在1380 cm-1左右检测到。然而，对于同一个4-MET分子而言，羧基在羟基磷灰石（HAP）表面形成盐与甲基丙烯酸基团中4-MET在表面附近的聚合是相互排斥的反应。
