Xu Bin, Gao Nai-yun, Rui Min, Wang Hong, Wu Hai-hui
State Key Laboratory of Pollution Control and Resource Reuse, Tongji University, Shanghai 200092, China.
Huan Jing Ke Xue. 2006 Feb;27(2):294-9.
The ozone oxidation of endocrine disruptor (bisphenol A) in drinking water was investigated. With the initial concentration of 1.0 mg/L, the removal efficiency of BPA (bisphenol A) could be measure up to 70%, 82%, 90% when the dosage of ozone was 1 mg/L, 1.5 mg/L, 2 mg/L respectively within 30 minutes. The impacts of BPA degradation under the conditions of different ozone dosages, different water background value, different BPA initial concentration and different ozone adding time were analyzed. The results show that ozone dosage play a dominant role during the process of BPA degradation, while the impact of the contact time could be ignored. The UV wavelength scanning is used to conform that the by-products were produced, which can be absorbed at UV254, and the UV254 keeps changing with the ozonation process. From the change of UV254, it can be drawn that BPA can not be completely degraded with low ozone dosage, while less adding time of total ozone dosage, high ozone dosage, improvement of dissolved ozone concentration will do great contribution to the extent of BPA degradation.
研究了饮用水中内分泌干扰物(双酚A)的臭氧氧化情况。在初始浓度为1.0 mg/L时,当臭氧投加量分别为1 mg/L、1.5 mg/L、2 mg/L时,30分钟内双酚A(BPA)的去除率分别可达70%、82%、90%。分析了不同臭氧投加量、不同水质背景值、不同BPA初始浓度以及不同臭氧投加时间条件下BPA降解的影响。结果表明,臭氧投加量在BPA降解过程中起主导作用,而接触时间的影响可忽略不计。采用紫外波长扫描确认了产生了可在UV254处吸收的副产物,且UV254随臭氧化过程不断变化。从UV254的变化可以看出,低臭氧投加量时BPA不能完全降解,而总臭氧投加量的添加时间越少、臭氧投加量越高、溶解臭氧浓度的提高对BPA降解程度有很大贡献。