Ripoll M, Winkler R G, Gompper G
Institut für Festkörperforschung, Forschungszentrum Jülich, D-52425 Jülich, Germany.
Phys Rev Lett. 2006 May 12;96(18):188302. doi: 10.1103/PhysRevLett.96.188302. Epub 2006 May 11.
Linear and star polymers in solution are studied in the presence of shear flow. The solvent is described by a particle-based mesoscopic simulation technique, which accounts for hydrodynamic interactions. The scaling properties of the average gyration tensor, the orientation angle, and the rotation frequency are investigated for various arm lengths and arm numbers. With increasing functionality f, star polymers exhibit a crossover in their flow properties from those of linear polymers to a novel behavior, which resembles the tank-treading motion of elastic capsules.
在剪切流存在的情况下,对溶液中的线性和星形聚合物进行了研究。溶剂通过基于粒子的介观模拟技术来描述,该技术考虑了流体动力学相互作用。针对不同的臂长和臂数,研究了平均回转张量、取向角和旋转频率的标度性质。随着官能度f的增加,星形聚合物的流动性质从线性聚合物的性质转变为一种新的行为,这种行为类似于弹性胶囊的平动。