Kawamura Yoko, Kawasaki Chie, Mine Sachika, Mutsuga Motoh, Tanamoto Kenichi
National Institute of Health Sciences, Tokyo, Japan.
Shokuhin Eiseigaku Zasshi. 2006 Apr;47(2):51-7. doi: 10.3358/shokueishi.47.51.
Levels of eight harmful elements, i.e., antimony, arsenic, barium, cadmium, chromium, lead, mercury and selenium, were investigated in 45 baby toys and 10 paints, which were mainly made of polyvinyl chloride. All samples contained barium at levels of 0.3-3,700 mg/kg, several samples contained cadmium (0.2-26 mg/kg), chromium (0.5-280 mg/kg) and lead (1.5-1,300 mg/kg), and one sample contained antimony (5.3 mg/kg). They might have been used as colorants of the toy materials and paints. They were then evaluated using the migration test of ISO 8124-3, in which samples were ground up, and then soaked in 0.07 mol/L HCl at 37 degrees C for two hours. Barium, cadmium, chromium and lead migrated from some of the samples, but at levels lower than the migration limits required by ISO 8124-3. Compared with the Japanese official method, the ISO method resulted in higher migration, but there are significant differences in the migration limits, test method, and so on between them. Further investigation is needed in this area.
对45个主要由聚氯乙烯制成的婴儿玩具和10种涂料中的8种有害元素,即锑、砷、钡、镉、铬、铅、汞和硒的含量进行了调查。所有样品中钡的含量为0.3 - 3700毫克/千克,有几个样品含有镉(0.2 - 26毫克/千克)、铬(0.5 - 280毫克/千克)和铅(1.5 - 1300毫克/千克),还有一个样品含有锑(5.3毫克/千克)。它们可能被用作玩具材料和涂料的着色剂。然后使用ISO 8124 - 3的迁移测试对其进行评估,在该测试中,将样品研磨,然后在37摄氏度下浸泡在0.07摩尔/升的盐酸中两小时。钡、镉、铬和铅从一些样品中迁移出来,但含量低于ISO 8124 - 3要求的迁移限值。与日本官方方法相比,ISO方法导致的迁移量更高,但它们在迁移限值、测试方法等方面存在显著差异。该领域需要进一步研究。